Padley Gorge is worth a visit through the day once the sun is up a bit - just not sure how much autumnal colour is showing through yet?
You could try Higger Tor, Mam Tor or Winnats Pass for sunrise as they are close enough to Padley to do sunrise then drive over.
There is always the chance of inversions at this time of year depending on conditions - all the above look great with a bit of mist.
A great all you can eat breakfast can be found here as well N53.2989625 W1.5576691 or at the cafe at the end of the Padley Gorge walk near the train station.
Plenty of other locations as well - just a few to consider
Dave.