The flash exposure is probably a tad too hot on the second shot (his cheek) but you've used a good lighting technique on both shots.
The second shot is using the ambient as a side light really nicely on the second shot, running slightly hotter than the fill from the flash coming in from the left.
What was the ambient exposure (shutter speed)? If you had room, say you're at 1/125th, then going up to 1/200th or even 1/250th would just add a bit more punch to the sky.
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